Famke Janssen makes a second appearance in our list as slinky Bond villainess Xenia Onatopp in GoldenEye. A former pilot in the Soviet Air Force, after the fall of communism, she is recruited by renegade Alex Trevelyan (Sean Bean) into his crime syndicate.
Deriving a sexual thrill through killing, she memorably offs a Canadian admiral during a bit of slap-and-tickle by crushing him to death between her thighs. More conventionally, she wastes a control room full of technicians with an AKSU-74 carbine while moaning orgasmically. She's not the sort of girl you bring home to your mum.
Fighting talk: "This time, Mr. Bond, the pleasure will be all mine."